A novel two-dimensional square grid cobalt complex: Synthesis, structure, luminescent and magnetic properties

Abstract: A novel cobalt(II) coordination polymer, [Co(L)2] n (1) (HL=4-(imidazol-1-yl)-benzoic acid), has been hydrothermally synthesized and structurally characterized by X-ray diffraction, IR spectrum and elemental analyses. Structure determination of complex 1 reveals that the two-dimensional (2D) network framework consists of regular square grid with dimensions of ca. 11.42×11.42Å. Complex 1 exhibits a strong blue luminescence centering at 409nm in the solid. Variable temperature magnetic susceptibility study shows there is a weak antiferromagnetic interaction in complex 1. Thermal property is also investigated. [Copyright &y& Elsevier]