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Observation of bimodal polyethylene derived from TiO2-supported zirconocene/MAO catalyst during polymerization of ethylene and ethylene/1-hexene.

Authors :
Jongsomjit, Bunjerd
Ngamposri, Sutti
Praserthdam, Piyasan
Source :
Catalysis Letters. Sep2007, Vol. 117 Issue 3/4, p177-181. 5p. 3 Charts, 3 Graphs.
Publication Year :
2007

Abstract

The bimodal polyethylene obtained from TiO2-supported zirconocene/MAO catalyst was observed during polymerization of ethylene and ethylene/1-hexene. By means of XPS, it revealed that TiO2 consisted of Ti3+ (BE = 462.6 eV) and Ti4+ (BE = 464.9 eV). The dual catalytic sites were attributed to the presence of Ti3+ and Ti4+ in TiO2. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
1011372X
Volume :
117
Issue :
3/4
Database :
Academic Search Index
Journal :
Catalysis Letters
Publication Type :
Academic Journal
Accession number :
26515714
Full Text :
https://doi.org/10.1007/s10562-007-9132-7