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Crystal Structure, (31P, 13C) MAS-NMR, IR Spectroscopy and Thermal Investigations of 2,6-Dimethylanilinium Dihydrogenmonophosphate Monohydrate.
- Source :
-
Phosphorus, Sulfur & Silicon & the Related Elements . Oct2007, Vol. 182 Issue 10, p2269-2282. 14p. 3 Diagrams, 5 Charts, 4 Graphs. - Publication Year :
- 2007
-
Abstract
- Chemical preparation, crystal structure, thermal analysis, IR absorption, and NMR studies are given for a new hybrid organic-inorganic compound, the (2,6-dimethyanilinium) dihydrogenophosphate monohydrate [C8H12N]H2PO4·H2O. This compound crystallizes in a triclinic P=1 unit-cell, with a = 7.392(5) Å, b = 8.323(3) Å, c = 10.306(5) Å, α = 95.769 (4)°, β = 102.642 (3)°, γ = 113.498(2)°, V = 554.88(5) Å3, and Z = 2. Its crystal structure is determined and refined to R = 0.040 with 1942 independent reflections. The atomic arrangement can be described by inorganic layers built by H2PO4- anions, and H2O molecules with which the organic molecules perform different interactions to form a stable 3D network. Solid state 31P and 13C CP-MAS-NMR spectroscopies are in agreement with the X-ray structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10426507
- Volume :
- 182
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Phosphorus, Sulfur & Silicon & the Related Elements
- Publication Type :
- Academic Journal
- Accession number :
- 26447516
- Full Text :
- https://doi.org/10.1080/10426500701418398