Measurement of the temperature dependence of line mixing and pressure broadening parameters between 296 and 90K in the ν 3 band of 12CH4 and their influence on atmospheric methane retrievals

Abstract: We measured the temperature dependence of the nitrogen broadening, narrowing and line-mixing coefficients of four lines of the P9 manifold in the ν 3 band of 12CH4 for atmospheric purposes. The data were collected using our tunable diode laser (TDL) spectrometer with active wavenumber control coupled to a newly developed cold Herriott cell with a path length of 5.37m and a temperature uniformity of better than 0.01K along the cell. We recorded and analyzed spectra recorded at sample temperatures between 90K and room temperature. We have investigated the influence of our new results in the inversion model used to retrieve methane profiles from atmospheric spectra; our new results make it possible to retrieve significantly more precise methane profiles. The atmospheric spectra we utilized were obtained by several of us with a balloon-born Fourier Transform infrared experiment in a limb configuration. Differences up to 7% on the retrieved volume mixing ratio were found compared to an inversion model using only HITRAN04 spectroscopic parameters. [Copyright &y& Elsevier]