Back to Search
Start Over
Synthesis and Characterization of a New Monophosphate (C6H6NCl2)(H2PO4) with an Interesting Chlorine-Mediated Framework.
- Source :
-
Phosphorus, Sulfur & Silicon & the Related Elements . Sep2007, Vol. 182 Issue 9, p2053-2068. 16p. 4 Diagrams, 4 Charts, 5 Graphs. - Publication Year :
- 2007
-
Abstract
- Chemical preparation, crystal structure, and NMR spectroscopy of a new monophosphate with 2,3-dichloroanilinium cation are given. This new compound crystallizes in the monoclinic system, with the space group P21/n and the following parameters: a = 11.031 (6), b = 6.007(3), c = 15.227(2) Å β = 98.98(4), V = 996.73(3) Å3, and Z = 4. The crystal structure has been determined and refined to R = 0.048 and Rw = 0.1317 using 2030 independent reflections. The structure can be described as clusters that aggregate with six organic molecules, resulting in a (1 0 [image omitted]) two dimensional sheet, and formation of arrays in three dimensions, via various interactions (H-bonds, electrostatic, Van der Waals). In addition, C─Cl...π interactions are observed as a consequence of the chlorine atom being flanked by two phenyl rings of the neighboring molecules. The structure has also short intermolecular Cl...Cl interactions [type I, Cl...Cl = 3.380(1) Å, C─Cl...Cl' = 132.26°]. This compound has also been investigated by IR, thermal analysis, and solid-state 13C and 31P MAS NMR spectroscopy combined with Ab Initio calculations. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10426507
- Volume :
- 182
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Phosphorus, Sulfur & Silicon & the Related Elements
- Publication Type :
- Academic Journal
- Accession number :
- 25915713
- Full Text :
- https://doi.org/10.1080/10426500701370300