A ∼3.5 Ga record of water-limited, acidic weathering conditions on Mars

Abstract: The secondary mineral budget on Earth is dominated by clay minerals, Al-hydroxides, and Fe-oxides, which are formed under the moderate pH, high water-to-rock ratio conditions typical of Earth''s near-surface environment. In contrast, geochemical analyses of rocks and soils from landed missions to Mars indicate that secondary mineralogy is dominated by Mg (±Fe, Ca)-sulfates and Fe-oxides. This discrepancy can be explained as resulting from differences in the chemical weathering environment of Earth and Mars. We suggest that chemical weathering processes on Mars are dominated by: (1) a low-pH, sulfuric acid-rich environment in which the stoichiometric dissolution of labile mineral phases such as olivine and apatite (±Fe–Ti oxides) is promoted; and (2) relatively low water-to-rock ratio, such that other silicate phases with slower dissolution rates (e.g., plagioclase, pyroxene) do not contribute substantially to the secondary mineral budget at the Martian surface. Under these conditions, Al-mobilization is limited, and the formation of significant Al-bearing secondary phases (e.g., clays, Al-hydroxides, Al-sulfates) is inhibited. The antiquity of rock samples analyzed in-situ on Mars suggest that water-limited acidic weathering conditions have more than likely been the defining characteristic of the Martian aqueous environment for billions of years. [Copyright &y& Elsevier]