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Bis[tris(1-pyrazolyl)methane-κ3 N, N′, N′′]copper(II) dichloride methanol disolvate.

Authors :
Silva, Telma F. S.
Martins, Luisa M. D. R.
Guedes da Silva, M. Fatima C.
Pombeiro, Armando J. L.
Source :
Acta Crystallographica: Section E. Jul2007, Vol. 63 Issue 7, pm1979-m1979. 1p. 2 Diagrams.
Publication Year :
2007

Abstract

The reaction between copper(II) chloride dihydrate and excess tris(1-pyrazolyl)methane results in the formation of the title complex, [Cu(C10H10N6)2]Cl2·2CH3OH. The centrosymmetric complex cation is mononuclear with octahedral coordination for Cu and two tridentate ligands. Two short and one long Cu—N distances [2.002 (3), 2.011 (2) and 2.413 (2) Å] are found, as expected for Jahn–Teller distortion. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
7
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
25700895
Full Text :
https://doi.org/10.1107/S1600536807024671