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Group 6 tetracarbonyl complexes of N-[(2-pyridyl)methyliden]-α (or β)-aminonaphthalene: Spectral characterization, electrochemistry, solvatochromism and photophysical studies
- Source :
-
Polyhedron . Jul2007, Vol. 26 Issue 12, p2433-2439. 7p. - Publication Year :
- 2007
-
Abstract
- Abstract: A new series of group 6 carbonyl complexes of N-[(2-pyridyl)methyliden]-α (or β)-aminonaphthalene (α/β-NaiPy) are described in this work. The complexes are formulated as cis-[M(CO)4(α/β-NaiPy)] by elemental, mass and other spectroscopic data. The complexes show emission spectra at room temperature and their quantum yield lies between 0.4 and 0.5. All the complexes exhibit negative solvatochromism. Cyclic voltammetry shows metal centred oxidation and ligand reductions. [Copyright &y& Elsevier]
- Subjects :
- *COMPLEX compounds
*SPECTRUM analysis
*ELECTROCHEMISTRY
*FLUORESCENCE
Subjects
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 26
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 25627930
- Full Text :
- https://doi.org/10.1016/j.poly.2006.12.029