Back to Search
Start Over
Hydrogen-bonding patterns in pyrimethamine tetrafluoroborate.
- Source :
-
Acta Crystallographica: Section E . Jun2007, Vol. 63 Issue 6, po2966-o2966. 1p. 4 Diagrams, 1 Chart. - Publication Year :
- 2007
-
Abstract
- The title compound [systematic name: 2,4-diamino-5-(4-chlorophenyl)-6-ethylpyrimdinium tetrafluoroborate], C12H14ClN4+·BF4−, is isomorphous with pyrimethamine perchlorate. The pyrimethamine (PMN) molecule is protonated at one of the pyrimidine N atoms. The protonated N atom and 2-amino group of the PMN cation interact with the tetrafluoroborate anion through a pair of N—H...F hydrogen bonds [graph set R22(8)]. The inversion-related PMN cations are linked through a pair of N—H...N hydrogen bonds. In addition to the base pairing, the F atoms bridge the 2-amino and 4-amino groups on either side of the paired bases, resulting in a complementary DADA array. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 63
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 25439567
- Full Text :
- https://doi.org/10.1107/S1600536807015656