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Effect of competitive acido complex formation of the solubility of binary chlorides in MCl2-M′Cl2-H2O systems.

Authors :
Zamyatin, I. V.
Skripkin, M. Yu.
Source :
Russian Journal of General Chemistry. Feb2007, Vol. 77 Issue 2, p226-233. 8p. 3 Charts, 5 Graphs.
Publication Year :
2007

Abstract

The solubility of d-metal halides in MCl2-M′Cl2-H2O systems with competitive complex formation at 25°C was discussed. The role of complex formation and hydration was traced. As the stability constants become closer to each other, the salting-in regions in the crystallization braches of both chlorides disappear. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10703632
Volume :
77
Issue :
2
Database :
Academic Search Index
Journal :
Russian Journal of General Chemistry
Publication Type :
Academic Journal
Accession number :
24602784
Full Text :
https://doi.org/10.1134/S1070363207020077