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Bis(1 H-imidazole-κ N3)bis­(4-methyl­benzoato-κ O)zinc(II) 4-methyl­benzoic acid disolvate.

Authors :
Chang-Sheng Gu
Xiao-Min Hao
Wen-Dong Song
Jian-Bin Yan
Source :
Acta Crystallographica: Section E. Mar2007, Vol. 63 Issue 3, pm895-m897. 1p. 2 Diagrams, 2 Charts.
Publication Year :
2007

Abstract

The mol­ecular structure of the title compound, [Zn(C8H7O2)2(C7H6N2)2]·2C8H8O2, is composed of a mononuclear ZnII complex, which possesses twofold rotation symmetry, and two uncoordinated 4-methyl­benzoic acid mol­ecules. The ZnII atom displays a four-coordinate distorted tetra­hedral configuration, formed by two carboxylate O atoms of two monodentate 4-methyl­benzoate ligands and two N atoms of two benzimidazole mol­ecules. In the crystal structure, complex mol­ecules are linked by the 4-methyl­benzoic acid mol­ecules via N—H⋯O and O—H⋯O hydrogen bonds, giving rise to the formation of a supra­molecular structure. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
3
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
24270723
Full Text :
https://doi.org/10.1107/S1600536807005715