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Antibody-metalloporphyrin catalytic assembly mimics natural oxidation enzymes.

Authors :
Nimri, Shai
Keinan, Ehud
Source :
Journal of the American Chemical Society. 10/06/99, Vol. 121 Issue 39, p8978. 5p. 15 Diagrams, 2 Charts, 3 Graphs.
Publication Year :
1999

Abstract

Presents an antibody-metalloporphyrin assembly that catalyzes the enantioselective oxidation of aromatic sulfides to sulfoxides. Extraction of antibody SN37.4 against water-soluble tin porphyrin; Enzyme characteristics; Enantioselective delivery of oxygen to the substrate; Michaelis-Menten saturation kinetics.

Subjects

Subjects :
*PORPHYRINS
*ANTIGEN-antibody reactions
*CATALYSTS
*OXIDATION
*SULFIDES

Details

Language :
English
ISSN :
00027863
Volume :
121
Issue :
39
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
2426986
Full Text :
https://doi.org/10.1021/ja990314q
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