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Anomalous cyclization of ethyl acetoacetate (3,6-dimethyl-4-oxo-3,4-dihydropyrimidin-2-yl)hydrazone.
- Source :
-
Russian Journal of General Chemistry . Jan2007, Vol. 77 Issue 1, p124-127. 4p. - Publication Year :
- 2007
-
Abstract
- Structural modification of some (pyrimidin-2-yl)hydrazones derived from ethyl acetoacetate via methylation at the N3 atom promotes anomalous cyclization to give [1,2,4]triazolo[1,5- a]pyrimidine derivatives. The mechanism of this transformation includes specific cleavage of the aliphatic fragment in the substrate with subsequent rearrangement of carbene-like intermediate. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 77
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 24207665
- Full Text :
- https://doi.org/10.1134/S1070363207010173