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Bis(1,4,7-triaza­cyclo­nona­ne-κ3 N)manganese(II) di-μ-diselenido-bis­[selenidoarsenate(III)].

Authors :
Kromm, Anna
Sheldrick, William S.
Source :
Acta Crystallographica: Section E. Feb2007, Vol. 63 Issue 2, pm581-m583. 1p. 2 Diagrams, 1 Chart.
Publication Year :
2007

Abstract

The title compound, [Mn(C6H15N3)2][As2Se6], contains a sandwich-like centrosymmetric complex cation with two tridentate 9-aneN3 (1,4,7-triaza­cyclo­nona­ne) ligands, which coordinate the MnII atom in an octa­hedral manner. AsSe3 pyramids are linked by two Se—Se bonds into the centrosymmetric chair-shaped six-membered ring of the [As2Se6]2− counter-anions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
2
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
23922487
Full Text :
https://doi.org/10.1107/S1600536807002760