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( S)-(–)-2,2′-Bis(2-methyl­allyl­oxy)-1,1′-binaphth­yl.

Authors :
Ricken, Stefan
Angelovski, Goran
Schürmann, Markus
Preut, Hans
Eilbracht, Peter
Source :
Acta Crystallographica: Section E. Feb2007, Vol. 63 Issue 2, po551-o552. 1p. 1 Diagram.
Publication Year :
2007

Abstract

The chiral title compound, C28H26O2, with potential uses in the synthesis of aza­macroheterocycles, shows a locked S-configuration for the binaphthyl unit. The diolefinic building blocks were prepared as diallylic ethers of ( S)-1,1′-binaphthol. The dihedral angle between the least-squares planes of the bicyclic ring systems is 68.53 (3)°. The mol­ecule resides on a twofold axis. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
2
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
23922216
Full Text :
https://doi.org/10.1107/S1600536806055498