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The first cyclopentadienyl complex of uranyl.
- Source :
-
Chemical Communications . Jan2007, Vol. 2007 Issue 5, p486-488. 3p. - Publication Year :
- 2007
-
Abstract
- The U(iv) linear pentacyano metallocene [U(C5Me5)2(CN)5][NEt4]3 reacted with 2 molar equivalents of pyridine N-oxide in THF or acetonitrile to give the U(vi) complex [UO2(C5Me5)(CN)3][NEt4]2, the first uranyl species containing the cyclopentadienyl ligand; the crystal structure revealed that the steric effects of the (C5Me5) ligand force the {UO2}2+ ion to deviate from linearity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PYRIDINE
*ACETONITRILE
*METALLOCENES
*HETEROCYCLIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 2007
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 23833858
- Full Text :
- https://doi.org/10.1039/b617700j