Hydrothermal stability of Fe-ZSM-5 and Fe-BEA prepared by wet ion-exchange for N2O decomposition

Abstract: The hydrothermal stability of WIE-based Fe-ZSM-5 and Fe-BEA for N2O decomposition in the presence of NO, H2O and O2 was studied at 723K. Catalysts were characterized with UV–vis, IR and Al-XANES. The N2O conversion remains at a constant level with Fe–H-BEA even in the presence of large amounts of H2O. Deactivation was, however, observed with Fe–H-ZSM-5 already in the presence of 0.5vol.% water. The analysis of deactivated samples indicated that steam-dealumination and clustering of iron occurred during the reaction with Fe-ZSM-5. Replacement of protons for sodium in Fe-ZSM-5 slowed down the rate of catalyst deactivation significantly. Steam-dealumination is likely to precede the clustering of iron in Fe–H-ZSM-5. The excellent hydrothermal stability of WIE-based Fe–H-BEA relates to the high initial degree of dealumination in the as-received BEA. [Copyright &y& Elsevier]