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Mild and efficient silylcyanation of ketones catalyzed by cesium fluoride

Authors :
Kim, Sung Soo
Rajagopal, Gurusamy
Song, Dae Ho
Source :
Journal of Organometallic Chemistry. May2004, Vol. 689 Issue 10, p1734-1738. 5p.
Publication Year :
2004

Abstract

An efficient method of addition of trimethylsilylcyanide to ketones by employing cesium fluoride as catalyst has been described. A variety of aromatic, aliphatic, cyclic and heterocyclic ketones have been converted into their corresponding trimethylsilyl ethers in excellent yield. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
0022328X
Volume :
689
Issue :
10
Database :
Academic Search Index
Journal :
Journal of Organometallic Chemistry
Publication Type :
Academic Journal
Accession number :
23487442
Full Text :
https://doi.org/10.1016/j.jorganchem.2004.01.025