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catena-Poly[[diaqua(isonicotinato-κ2 O, O′)dysprosium(III)]-di-μ-isonicotinato-κ4 O: O′].
- Source :
-
Acta Crystallographica: Section E . Nov2006, Vol. 62 Issue 11, p2952-2954. 3p. 4 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- The title dysprosium coordination polymer [Dy(IN)3(H2O)2] n, where IN− is the isonicotinate anion C6H4NO2−, has been hydro­thermally synthesized. The polymer exhibits a doubly carboxyl­ate-bridged infinite chain-like structure with the metal center lying on a crystallographic twofold axis and coordinating by two carboxyl­ate O atoms from a chelating isonicotinate group (also lying on a twofold axis), four carboxyl­ate O atoms from four bridging isonicotinate ligands, and two water mol­ecules, to yield an eight-coordinate square-anti­prismatic geometry. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 23000165
- Full Text :
- https://doi.org/10.1107/S1600536806041559