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Modeling the Hydrodesulfurization Reaction at Nickel. Unusual Reactivity of Dibenzothiophenes...
- Source :
-
Journal of the American Chemical Society . 08/25/99, Vol. 121 Issue 33, p7606. 12p. 16 Diagrams, 2 Charts, 1 Graph. - Publication Year :
- 1999
-
Abstract
- Presents a study which examined the reactivity of a nickel hydride complex toward carbon-sulfur bond activation in thiophenic molecules. Preparation of the nickel hydride dimer; Reactions with thiopene and benzothiopene; Preparation of sulfur-bridged dinuclear complexes; Mechanism of desulfurization of dibenzothiopene; Conclusions.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 121
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 2297751
- Full Text :
- https://doi.org/10.1021/ja9905997