Progressive damage during thermal shock cycling of D-gun sprayed thermal barrier coatings with hollow spherical ZrO2–8Y2O3

Abstract: Thermal shock cycling behaviors of D-gun sprayed TBCs with a hollow spherical ZrO2–8Y2O3 (HSP-YSZ) top coat and NiCrAlY bond coat on directionally solidified Ni-base superalloys DZ125 were investigated at high temperature (1100°C)↔room temperature (RT) repeatedly by water quenching. Scanning electron microscopy (SEM) was used to characterize the coating microstructure and failure morphology. The results showed that failure of the D-gun sprayed TBC starts with crack initiation along the splats boundary in the ceramic top coat and the non-alumina oxides. The cracks propagate and coalesce with the increasing thermal cycling. The extensive cracking of the rapidly formed non-alumina oxides, resulting from the depletion of aluminum in the bond coat, aids to delamination of the outer ceramic layer. The stress distributions in TGO layer at different thermal shock cycles was measured by luminescence spectroscopy to investigate the failure mechanism of TBC system. [Copyright &y& Elsevier]