Vapor–liquid equilibria for nitrogen with 2-hexanol, 2-heptanol, or 2-octanol binary systems

Abstract: Isothermal vapor–liquid equilibrium (VLE) data were measured for the binary systems of nitrogen with 2-hexanol, 2-heptanol, or 2-octanol at temperatures from 333.15 to 393.15K and pressure up to 100bar. Henry''s constants of nitrogen in these three sec-alcohols were determined by using the Krichevesky–Ilinskaya equation. The experimental VLE data were also correlated by the Peng–Robinson and the Patel–Teja equations of state with various mixing rules. [Copyright &y& Elsevier]