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Poly[[μ-aqua-tetra-μ-thiocyanato-manganese(II)mercury(II)] sulfolane solvate].
- Source :
-
Acta Crystallographica: Section E . Sep2006, Vol. 62 Issue 9, pm2249-m2251. 3p. 3 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- The title polymeric compound, {[MnHg(SCN)4(H2O)]-C4H8O2S}n, consists of slightly distorted MnN4O2 octahedra and HgS4 tetrahedra. Each MnII ion is bound to N atoms belonging to the thiocyanate (SCN) groups and to two O atoms of adjacent water ligands. The sulfolane molecule connects with the coordinated water molecule through hydrogen bonding. Each HgII atom is coordinated by four SCN S atoms. The two adjacent MnII atoms and two O atoms of bridging water molecules connect with one another and form a parallelogram. Each pair of MnII and HgII atoms is connected by an -SCN- bridge, forming an infinite three-dimensional structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 22243729
- Full Text :
- https://doi.org/10.1107/S160053680603176X