CoSi2 growth on Si(001) by reactive deposition epitaxy: Effects of high-flux, low-energy ion irradiation.

CoSi2 layers, <40 nm thick, were grown on Si(001) by reactive deposition epitaxy (RDE) in which Co was deposited at 700 °C by magnetically unbalanced ultrahigh vacuum magnetron sputtering. X-ray diffraction pole figures and transmission electron microscopy (TEM) reveal that the layers, which exhibit a cube-on-cube epitaxial relationship with the substrate, (001)CoSi2∥(001)Si and [100]CoSi2∥[100]Si, contain fourfold symmetric {111} twinned domains oriented such that {221}CoSi2∥(001)Si and <110>CoSi2∥[110]Si. We demonstrate that high-flux low-energy (EAr+=9.6 eV) Ar+ ion irradiation during deposition dramatically increases the area fraction fu of untwinned regions from 0.17 in films grown under standard magnetically balanced conditions in which the ratio JAr+/JCo of the incident Ar+ to Co fluxes is 1.4 to 0.72 with JAr+/JCo=13.3. TEM analyses show that the early stages of RDE CoSi2(001) film growth proceed via the Volmer-Weber mode with independent nucleation of both untwinned and twinned islands. Increasing JAr+/JCo results in larger values of both the number density and area of untwinned with respect to twinned islands. The intense Ar+ ion bombardment creates additional low-energy adsorption sites that favor the nucleation of untwinned islands while collisionally enhancing Co surface mobilities which, in turn, increases the probability of itinerant Co adatoms reaching these sites. [ABSTRACT FROM AUTHOR]