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Hydrogen-bonding patterns in 2-amino-4,6-dimethoxy­pyrimidine–4-amino­benzoic acid (1/1).

Authors :
Thanigaimani, Kaliyaperumal
Lynch, Daniel E.
Muthiah, Packianathan Thomas
Source :
Acta Crystallographica: Section E. Jul2006, Vol. 62 Issue 7, po2976-o2978. 1p. 4 Diagrams, 1 Chart.
Publication Year :
2006

Abstract

In the title cocrystal, C6H9N3O2·C7H7NO2, the 2-amino-4,6-dimethoxy­pyrimidine mol­ecule inter­acts with the carboxyl group of the 4-amino­benzoic acid mol­ecule through N—H⋯O and O—H⋯N hydrogen bonds, forming a cyclic hydrogen-bonded motif [ R22(8)]. This motif further self-organizes through N—H⋯O hydrogen bonds to generate an array of six hydrogen bonds with the rings having the graph-set notation R23(6), R22(8), R42(8), R22(8) and R23(6). The 4-amino­benzoic acid mol­ecules self-assemble via N—H⋯O hydrogen bonds to form a supra­molecular chain along the c axis. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
7
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
21509198
Full Text :
https://doi.org/10.1107/S1600536806023130