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Synthesis of 2-Alkylidenepyrrolidines and Pyrroles by Condensation of 1,3-Dicarbonyl Dianions with a-Azidoketones and Subsequent Intramolecular Staudinger-Aza-Wittig Reaction.

Authors :
Freifeld, Lila
Shojaei, Heydar
Langer, Peter
Source :
Journal of Organic Chemistry. 6/23/2006, Vol. 71 Issue 13, p4965-4968. 4p. 2 Diagrams, 1 Chart.
Publication Year :
2006

Abstract

The condensation of 1,3-dicarbonyl dianions with α-azidoketones afforded open-chained condensation products that were transformed into pyrroles by Staudinger-aza-Wittig reactions and the subsequent treatment with trifluoroacetic acid. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00223263
Volume :
71
Issue :
13
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
21408733
Full Text :
https://doi.org/10.1021/jo060593h