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Application of hydrophilic ionic liquids as co-solvents in chloroperoxidase catalyzed oxidations

Authors :
Chiappe, Cinzia
Neri, Lisa
Pieraccini, Daniela
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jul2006, Vol. 47 Issue 29, p5089-5093. 5p.
Publication Year :
2006

Abstract

Abstract: The effect of hydrophilic ionic liquids (ILs) on the activity of chloroperoxidase (CPO) was checked through kinetic and stereochemical studies. The possibility to employ this enzyme in synthesis has been demonstrated investigating the chemo- and stereoselectivity of oxidation of phenyl methylsulfide in several citrate buffer–IL mixtures. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
47
Issue :
29
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
21187517
Full Text :
https://doi.org/10.1016/j.tetlet.2006.05.072