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Butyltriphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III).
- Source :
-
Acta Crystallographica: Section E . Jun2006, Vol. 62 Issue 6, pm1419-m1421. 1p. 3 Diagrams, 1 Chart. - Publication Year :
- 2006
-
Abstract
- In the title complex, (C22H24P)[Ni(C3S5)2] or (BuPh3P)[Ni(dmit)2] (where BuPh3P is the butyl­triphenyl­phospho­nium cation and dmit is the 2-thioxo-1,3-dithiole-4,5-dithiol­ate anion), each Ni atom is tetra­coordinated by four dmit S atoms, forming a nearly square-planar arrangement. The average Ni—S bond length is 2.16Å, much smaller than 2.21Å for the Ni2+ ion in [Ni(dmit)2]2−. The other bond distances are also shorter, close to the corresponding double-bond value. The [Ni(dmit)2]− anions and butyl­triphenyl­phospho­nium counter-cations form a layered arrangement in the crystal structure. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NICKEL compounds
*ATOMS
*ANIONS
*CATIONS
*DITHIOLE
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 21073614
- Full Text :
- https://doi.org/10.1107/S1600536806019210