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Fabrication and Characterization of Novel Salicylic Acid Sensors Using Different Reagents (Ferric and Copper).

Authors :
Loh, HanChern
Ahmad, Musa
Taib, MohdNasir
Source :
Analytical Letters. 2006, Vol. 39 Issue 7, p1299-1310. 12p. 2 Diagrams, 6 Graphs.
Publication Year :
2006

Abstract

Fabrication of optical fiber salicylic acid (SA) sensors based on immobilization of ferric(III) nitrate and copper(II) acetate on Dowex‐50x8 is presented in this paper. The SA forms a stable purple complex with immobilized Fe 3+ at pH 2.1 with a response time of 10 min while it forms a stable yellowish green complex with immobilized Cu 2+ at pH 6.5 with a response time of 8 min. The reflectance spectra of the sensors were measured by using an optical fiber spectrophotometer. The results showed these SA sensors have maximum reflectance at 786 nm and 725 nm for SAFe complex and SACu complex, respectively. The useful dynamic response ranges are 0.02–0.50 g/L (SAFe) and 0.40–1.40 g/L (SACu). These complexes are stable for more than 24 hours. A good reproducibility (0.90%— SAFe; 0.86%— SACu) of measurement was obtained with these sensors. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00032719
Volume :
39
Issue :
7
Database :
Academic Search Index
Journal :
Analytical Letters
Publication Type :
Academic Journal
Accession number :
21007756
Full Text :
https://doi.org/10.1080/00032710600666354