Synthesis and Characterization of Aluminum-Containing Tin(IV) Heterobimetallic Sulfides.

Authors :: Zhi Yang
Xiaoli Ma
Jancik, Vojtech
Zhensheng Zhang
Roesky, Herbert W.
Magull, Jörg
Noltemeyer, Mathias
Schmidt, Hans-Georg
Cea-Olivares, Raymundo
Toscano, Rubén A.
Source :: Inorganic Chemistry. 4/17/2006, Vol. 45 Issue 8, p3312-3315. 4p. 4 Diagrams, 4 Charts.
Publication Year :: 2006
Abstract: Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAI(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-/Pr2C6H3] with Ph2SnCl2, Me2SnCl2, and SnCl4 in THF respectively afforded LAl(μ-S)2SnPh2 (2), LAl(μ-S)2SnMe2 (3), and LAl(μ-S)2Sn(μ-S)2AIL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis. [ABSTRACT FROM AUTHOR]

Subjects :: *ALUMINUM
*ASYMMETRIC synthesis
*ASYMMETRY (Chemistry)
*PARTICLES (Nuclear physics)
*HYDROGEN-ion concentration
*MASS spectrometry
*X-ray diffraction
*SPECTRUM analysis

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