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Strategies for Electrooptic Film Fabrication. Influence of Pyrrole-Pyridine-Based Dibranched Chromophore Architecture on Covalent Self-Assembly, Thin-Film Microstructure, and Nonlinear Optical Response.
- Source :
-
Journal of the American Chemical Society . 2/15/2006, Vol. 128 Issue 6, p2142-2153. 12p. - Publication Year :
- 2006
-
Abstract
- The new dibranched, heterocyclic "push-pull" chromophores bis{ 1 -(pyridin-4-yl)-2-[2-(N-methyl- pyrrol-5-yl)]ethane}methane (1), 1 -(pyrid-4-yl)-2-(N-methyl-5-formylpyrrol-2-yl)ethylene (2), { 1 -(N-methyl- pyridinium-4-yl)-2-[2-(N-methylpyrrol-5-yl)]ethane}{(1 -(pyridin-4-yl)-2-[2-(N-methylpyrrol-5-yl)lethane}- methane (3), N-methyl-2-[1 -(N-methylpyrid-4-yl)ethen-2-yl]-5-[pyrid-4-yl]ethen-2-yl]pyrrole iodide (4), bis- {1-(N-methyl-4-pyridinio)-2-[2-(N-methylpyrrol-5-yl)]ethane}methane iodide (5), and N-methyl-2,5-[1-(N- methylpyrid-4-yl)ethen-2-yl]pyrrole iodide (6) have been synthesized and characterized. The neutral (1 and 2) and monomethyl salts (3 and 4) undergo chemisorptive reaction with iodobenzyl-functionalized surfaces to afford chromophore monolayers SA-1/SA-2 and SA-3/SA-4, respectively. Molecular structures and other physicochemical properties have been defined by 1H NMR, optical spectroscopy, and XRD. Thin-film characterization by a variety of techniques (optical spectroscopy, specular X-ray reflectivity, atomic force microscopy, X-ray photoelectron spectroscopy, and angle-dependent polarized second harmonic generation) underscore the importance of the chromophore molecular architecture as well as film growth method on film microstructure and optical/electrooptic response. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 128
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 20080052
- Full Text :
- https://doi.org/10.1021/ja057556c