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(1,3-Dioxan-2-ylmethyl)triphenylphosphonium bromide monohydrate.
- Source :
-
Acta Crystallographica: Section E . Mar2006, Vol. 62 Issue 3, po933-o934. 1p. 2 Diagrams, 1 Chart. - Publication Year :
- 2006
-
Abstract
- In the crystal structure of the title phospho­nium salt, C22H22O2P+·Br−·H2O, the triphenyl­phospho­sphonium group has three P—C bonds to phenyl rings which are equal within experimental error [mean 1.782 (3) Å] The P atom is also attached directly to the C atom of a 1,3-dioxan-2-ylmethyl group with a longer P—C bond of 1.800 (3) Å. The C—C bond of the dioxane ring [1.418 (5) Å] is shorter than the normal bond distance. The asymmetric unit contains two bromide anions on twofold rotation axes to balance the charge of the cation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BROMIDES
*SALT
*ATOMS
*ANIONS
*CATIONS
*HYDROGEN bonding
*ORGANIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 19995878
- Full Text :
- https://doi.org/10.1107/S1600536806003783