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[11,23-Dimethyl-15,19-diaza-3,7-diazo­niatricyclo­[19.3.1.19,13]tetracosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ4 N15, N19, O, O′]tris­(nitrato-κ2 O, O′)samarium(III)

Authors :
Philouze, Christian
du Moulinet d'Hardemare, Amaury
Jarjayes, Olivier
Source :
Acta Crystallographica: Section E. Feb2006, Vol. 62 Issue 2, pm227-m228. 1p. 2 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

In the title compound, [Sm(NO3)3(C24H28N4O2)], the Sm atom has tenfold coordination, built up from two imino N atoms, two deprotonated phenolic O atoms and three bidentate nitrate groups. The Sm ion is incorporated in an out-of-plane position relative to the macrocyclic ligand, which adopts a folded conformation. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
2
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
19642447
Full Text :
https://doi.org/10.1107/S1600536805041504