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Interactions between xenon and phospholipid bicelles studied by 2H/129Xe/131Xe NMR and optical pumping of nuclear spins
- Source :
-
Chemical Physics Letters . Feb2006, Vol. 419 Issue 1-3, p233-239. 7p. - Publication Year :
- 2006
-
Abstract
- Abstract: The interactions between xenon and DMPC/DHPC bicelles (q =3.5%,7.5%w/v) were studied via 2H, 129Xe, 131Xe, and optically enhanced 129Xe NMR. The chemical shifts, linewidths, and quadrupolar couplings of the xenon/bicelle NMR signals were correlated with different regions of the bicellar phase diagram. The addition of xenon (<70mM) was observed to reduce the temperature-onset of bicelle alignment by several degrees, in quantitative agreement with effects previously observed with chloroform; however, the stable liquid-crystalline range was not significantly reduced. Preliminary laser-polarized xenon/bicelle studies yielded 129Xe T 1 values of ∼120s, long enough to permit a variety of planned experiments. [Copyright &y& Elsevier]
- Subjects :
- *NOBLE gases
*NUCLEAR magnetic resonance
*CHLOROHYDROCARBONS
*TRIHALOMETHANES
Subjects
Details
- Language :
- English
- ISSN :
- 00092614
- Volume :
- 419
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Chemical Physics Letters
- Publication Type :
- Academic Journal
- Accession number :
- 19591488
- Full Text :
- https://doi.org/10.1016/j.cplett.2005.11.086