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Unbinding and preunbinding in surfactant solutions.

Authors :
Komura, S.
Shimokawa, N.
Kato, T.
Source :
Journal of Chemical Physics. 1/21/2006, Vol. 124 Issue 3, p034906. 7p. 7 Graphs.
Publication Year :
2006

Abstract

We propose models for the first-order unbinding transition of lyotropic lamellae in surfactant solutions. The coupling between the surfactant volume fraction and the elastic degree of freedom is considered so that the net attractive interaction between the surfactant molecules is enhanced. The elastic degree of freedom can be either (i) a membrane elastic degree of freedom or (ii) a bulk elastic degree of freedom. The phase behaviors of these two models are analyzed. For both cases, the unbinding transition becomes first order when the coupling is strong enough. We determine the associated preunbinding line which separates two lamellar phases having different repeat distances. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
124
Issue :
3
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
19529484
Full Text :
https://doi.org/10.1063/1.2159475