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Synthesis and functionalization of ethylene/p-allyltoluene copolymer
- Source :
-
Reactive & Functional Polymers . Dec2005, Vol. 65 Issue 3, p285-292. 8p. - Publication Year :
- 2005
-
Abstract
- Abstract: A new reactive comonomer, p-allyltoluene (p-AT), was synthesized and copolymerized with ethylene by catalyst system of Et(Ind)2ZrCl2/MAO. The reactivity ratios of ethylene and p-AT were calculated. The lithiation reaction of PE copolymer was performed efficiently and the results showed that the reactions were occurred on the side chain but not on the backbone of the copolymer. PE-g-PS and PE-g-PDMS were synthesized via graft-from anionic polymerization to modify polyethylene. The results of Molau test showed that PE-g-PS could be potential good compatilizer. [Copyright &y& Elsevier]
- Subjects :
- *ETHYLENE
*COPOLYMERS
*CHEMICAL reactions
*ADDITION polymerization
Subjects
Details
- Language :
- English
- ISSN :
- 13815148
- Volume :
- 65
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Reactive & Functional Polymers
- Publication Type :
- Academic Journal
- Accession number :
- 19059944
- Full Text :
- https://doi.org/10.1016/j.reactfunctpolym.2005.06.011