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Ferrocenyl bis-phosphine ligands bearing sulfinyl, sulfonyl or sulfenyl groups: applications in asymmetric hydrogenation and allylic alkylation reactions
- Source :
-
Tetrahedron: Asymmetry . Nov2005, Vol. 16 Issue 22, p3676-3681. 6p. - Publication Year :
- 2005
-
Abstract
- Abstract: A new series of chiral ferrocenyl bis-phosphine ligands have been synthesized. Elements of planar and central chirality have been incorporated into a ferrocene backbone through sulfinyl, sulfonyl and sulfenyl groups at the ortho-position to the phosphines. The effectiveness of these ligands has been demonstrated in Rh-catalyzed hydrogenations and Pd-catalyzed allylic alkylations. [Copyright &y& Elsevier]
- Subjects :
- *PHOSPHORUS compounds
*CHEMICAL reactions
*LIGANDS (Chemistry)
*HYDROCARBONS
Subjects
Details
- Language :
- English
- ISSN :
- 09574166
- Volume :
- 16
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Tetrahedron: Asymmetry
- Publication Type :
- Academic Journal
- Accession number :
- 19059254
- Full Text :
- https://doi.org/10.1016/j.tetasy.2005.08.036