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Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H3PW12O40/SiO2 under an O2 atmosphere

Authors :
Farhadi, Saeid
Afshari, Mozhgan
Maleki, Mansoureh
Babazadeh, Zaynab
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Dec2005, Vol. 46 Issue 49, p8483-8486. 4p.
Publication Year :
2005

Abstract

Abstract: An efficient, selective and green procedure for the photocatalytic oxidation of primary and secondary benzylic alcohols to the corresponding aldehydes and ketones has been achieved using silica-encapsulated H3PW12O40 as a recyclable heterogeneous photocatalyst in acetonitrile under oxygen gas as the sole reoxidant of the catalyst. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
46
Issue :
49
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
18980766
Full Text :
https://doi.org/10.1016/j.tetlet.2005.10.019