Back to Search Start Over

Bis[(diphenyl­phosphino)acetato-κ2 O, P]palladium(II) dichloro­methane solvate.

Authors :
Meng-Ping Guo
Fang-Fang Jian
Ren He
Hai-Lian Xiao
Source :
Acta Crystallographica: Section E. Aug2005, Vol. 61 Issue 8, pm1635-m1636. 2p. 2 Diagrams, 2 Charts.
Publication Year :
2005

Abstract

The title compound, [Pd(C14H12O2P)2]·CH2Cl2, consists of mononuclear [(Ph2PCH2COO)2Pd] complexes and dichloro­methane mol­ecules in a 1:1 molar ratio. The two (diphenyl­phosphino)acetate ligands are coordinated to the central Pd atom by their P and O atoms, forming five-membered chelate rings. The PdII atom has a distorted square-planar configuration [Pd—O = 2.076 (3) and 2.082 (3) Å, and Pd—P = 2.214 (1) and 2.216 (1) Å]. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
8
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18818788
Full Text :
https://doi.org/10.1107/S160053680502341X