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Polymeric bis( N-methylformamide)tetrathiocyanatocadmium(II)mercury(II).
- Source :
-
Acta Crystallographica: Section E . Jun2005, Vol. 61 Issue 6, pm1147-m1149. 3p. 2 Diagrams, 1 Chart. - Publication Year :
- 2005
-
Abstract
- The title complex, poly­[bis( N-methyl­form­amide)­tetra-μ-thio­cyanatocadmium(II)­mercury(II)], [CdHg(NCS)4(C2H5NO)2] n, contains slightly distorted octahedral CdN4O2 and tetrahedral HgS4. The CdII atom is coordinated by the N atoms of four SCN groups and O atoms of two N-methyl­form­amide ligands in a cis orientation. The HgII atom is coordinated by S atoms of one independent and three symmetry-related SCN groups. The two metal atoms, viz. CdII and HgII, are connected by an —S=C=N— bridge, forming an infinite three-dimensional network. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METHYL groups
*ATOMS
*CADMIUM
*PHYSICAL & theoretical chemistry
*ORGANIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 61
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 18818446
- Full Text :
- https://doi.org/10.1107/S1600536805015394