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Bis(2,2′-bi­pyridine-κ2 N,N′)­chloro­copper(II) tetra­fluoro­borate di­chloro­methane solvate.

Authors :
Linfang Jia
Qi Yin
Mingming Yu
Zhanxian Li
Wenfu Fu
Junfeng Zhang
Source :
Acta Crystallographica: Section E. Jun2005, Vol. 61 Issue 6, pm1039-m1041. 3p. 2 Diagrams, 1 Chart.
Publication Year :
2005

Abstract

The new mononuclear copper(II) complex, [CuCl(C10H8N2)2]BF4·CH2Cl2, was prepared by a new procedure using photo-irradiation and a nitro­gen atmosphere. X-ray analysis reveals a slightly distorted trigonal–bipyramidal coordination geometry of copper(II); the axial ligands and the CuII atom deviate slightly from linearity [N—Cu—N = 175.3 (3)°]. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
6
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18818339
Full Text :
https://doi.org/10.1107/S1600536805013760