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4-Phenyl­pyridinium betaine of squaric acid.

Authors :
Kolev, Tonsko
Wortmann, Rüdiger
Spiteller, Michael
Sheldrick, William Stephen
Mayer-Figge, Heike
Source :
Acta Crystallographica: Section E. Apr2005, Vol. 61 Issue 4, po1090-o1092. 3p. 2 Color Photographs, 1 Chart.
Publication Year :
2005

Abstract

The title compound, 4-phenyl­pyridinium-3-squarate, C15H9NO3, exhibits an inter­planar angle between the pyridinium and squarate rings of 0.6 (1)°. It displays a dipolar electronic ground-state structure, with a positively charged pyridinium fragment and a negatively charged squarate moiety. In the mol­ecule, the two aromatic rings are twisted by 31.6 (1)°. The bond lengths within the squarate system represent average values for the two possible resonance structures, with a central typical carbon­yl bond [1.203 (2) Å] flanked by two longer `semicarbon­yl' bonds of lengths 1.228 (2) and 1.221 (2) Å. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
4
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18817980
Full Text :
https://doi.org/10.1107/S1600536805008457