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Bis(tetraethylammonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II).
- Source :
-
Acta Crystallographica: Section E . Apr2005, Vol. 61 Issue 4, pm717-m719. 3p. 2 Diagrams, 1 Chart. - Publication Year :
- 2005
-
Abstract
- In the title complex, (C8H20N)2[Cu(C3S5)2], each Cu atom is tetracoordinated by four dmit S atoms (dmit is 2-thio­xo-1,3-di­thiole-4,5-di­thiol­ate), forming a slightly distorted square-planar arrangement. The average Cu—S bond length is a little larger than the sum of the single-bond covalent radii. The S—Cu—S bond angles for the vicinal S atoms are somewhat larger than the typical right angle and the other two angles are much smaller than 180°. The [Cu(dmit)2]2− anions and tetraethyl­ammonium counter-cations form a layered arrangement in the crystal structure. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ATOMS
*SELENIUM
*DITHIOLE
*CATIONS
*MOLECULAR structure
*LIGANDS (Chemistry)
*IONS
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 61
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 18817914
- Full Text :
- https://doi.org/10.1107/S1600536805008159