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Poly­[[bis­(tri­phenyl­phosphine)­mercury(II)]-μ-thio­cyanato-cadmium(II)-tri-μ-thio­cyanato].

Authors :
Dong Xu
Xin Qiang Wang
Wen Tao Yu
Hai Qing Sun
Source :
Acta Crystallographica: Section E. Mar2005, Vol. 61 Issue 3, pm548-m550. 3p. 3 Diagrams, 1 Chart.
Publication Year :
2005

Abstract

The title complex, [CdHg(NCS)4(C18H15P)2] n, contains slightly distorted trigonal bipyramidal CdN4S and tetrahedral HgP2S2. The CdII atom is coordinated by the N atoms of four thio­cyanate ions and the S atom of one thio­cyanate ion. The HgII atom is coordinated by two tri­phenyl­phosphine P atoms and two thio­cyanate S atoms. The two metal atoms, viz. CdII and HgII, are connected by an —S=C=N— bridge, forming an infinite three-dimensional network. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
3
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18817706
Full Text :
https://doi.org/10.1107/S160053680500468X