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Tetraaquadithiocyanatonickel(II) tetrakis(2-amino-4,6-dimethylpyrimidine) dihydrate.
- Source :
-
Acta Crystallographica: Section E . Feb2005, Vol. 61 Issue 2, pm204-m206. 3p. 5 Diagrams, 2 Charts. - Publication Year :
- 2005
-
Abstract
- In the title complex, [Ni(NCS)2(H2O)4]·4C6H9N3·2H2O, the nickel(II) ion occupies an inversion centre and is octahedrally coordinated by two N-bonded thio­cyanate ions and four water mol­ecules. The two distinct 2-amino-4,6-di­methyl­pyrimidine mol­ecules adopt distinct base-pairing dimerization patterns via different pairs of N—H⋯N bonds. They are also hydrogen bonded to the coordinated and uncoordinated water mol­ecules and thio­cyanate ions through O—H⋯O, O—H⋯S(thio­cyanate) and N—H⋯N(thio­cyanate) hydrogen bonds. [ABSTRACT FROM AUTHOR]
- Subjects :
- *COMPLEX compounds
*HYDRATES
*NICKEL
*THIOCYANATES
*IONS
*HYDROGEN bonding
*HYDROGEN
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 61
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 18817498
- Full Text :
- https://doi.org/10.1107/S1600536804033884