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Ethyl­enediammonium diaqua­bis(ethyl­enediamine-κ2 N, N′)zinc(II) bis(pyridine-2,6-dicarboxyl­ato-κ3, O, N, O′)zincate(II) dihydrate.

Authors :
Ai-Yun Fu
Da-Qi Wang
De-Zhi Sun
Source :
Acta Crystallographica: Section E. Feb2005, Vol. 61 Issue 2, pm401-m403. 3p. 3 Diagrams, 2 Charts.
Publication Year :
2005

Abstract

In the title compound, (C2H10N2)[Zn(C2H8N2)2(H2O)2][Zn(C7H3NO4)2]2·2H2O, the Zn atom (site symmetry 2/ m) in the [Zn(C2H8N2)2(H2O)2]2+ cation is six-coordinated by four N atoms from bidentate ethyl­enediammonium molecules and two water O atoms. The Zn atom (site symmetry 2) in the [Zn(C7H3NO4)2]2− anion is six-coordinated by four O atoms and two N atoms from two tridentate pyridine-2,6-dicarboxyl­ate ligands. An uncoordinated ethyl­enediammonium cation and two water mol­ecules are also present in the structure. The crystal packing is stabilized by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional network. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
2
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18817488
Full Text :
https://doi.org/10.1107/S1600536805002576