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Tris(ethylenediamine-κ2 N,N′)zinc(II) bis[2,3-dimercaptobutenedinitrile(2–)-κ2 S,S′]zincate(II).
- Source :
-
Acta Crystallographica: Section E . Nov2004, Vol. 60 Issue 11, pm1736-m1737. 2p. 3 Diagrams, 1 Chart. - Publication Year :
- 2004
-
Abstract
- The title complex, [Zn(C2H8N2)3][Zn(C4N2S2)2], exists as discrete ions, both of which lie on twofold rotation axes. The [Zn(C2H8N2)3]2+ cation exhibits a slightly distorted octahedral geometry. In the [Zn(C4N2S2)2]2− anion, the ZnII atom is surrounded by two chelating ligands in a distorted tetrahedral geometry. The crystal structure is stabilized by hydrogen bonds of the types N—H⋯N and N—H⋯S. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 60
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 18816944
- Full Text :
- https://doi.org/10.1107/S160053680402714X