Back to Search Start Over

Di­aqua­bis(7-iodo-8-oxidoquinolinium-5-sulfonato)­strontium(II) monohydrate.

Authors :
Balasubramani, Kasthuri
Francis, Savarimuthu
Muthiah, Packianathan Thomas
Bocelli, Gabriele
Cantoni, Andrea
Source :
Acta Crystallographica: Section E. Nov2004, Vol. 60 Issue 11, pm1576-m1579. 4p. 4 Diagrams, 3 Charts.
Publication Year :
2004

Abstract

The title compound, [Sr(C9H5INO4S2)2(H2O)2]·H2O, is isomorphous with the corresponding calcium complex of ferron (8-hydroxy-7-iodo­quinoline-5-sulfonic acid). The asymmetric unit consists of one SrII ion, two organic ligands, two coordinated water mol­ecules and one uncoordinated water mol­ecule. The SrII ion has a pentagonal–bipyramidal coordination geometry made up of O atoms of three different sulfonate groups, deprotonated quinolinol O atoms of two different oxine rings and two water mol­ecules. In the ligands of type I, two O atoms of the sulfonate group are involved in coordination, whereas in type II ligands, only one O atom is involved. Ligands of type I are stacked on top of one another, each pair of adjacent members of the stack being related by an inversion centre. Ligands of type II are also stacked in a similar manner. These molecular stacks are cross-linked by Sr—O(sulfonate) and Sr—O(quinolinol) bonds, leading to an extended framework. This architecture is further stabilized by a number of O—H⋯O and N—H⋯O hydrogen bonds. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
60
Issue :
11
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18816897
Full Text :
https://doi.org/10.1107/S1600536804024067