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10-( tert-Butyldimethylsilyl)-4,6-bis(diphenylphosphino)phenoxazine.
- Source :
-
Acta Crystallographica: Section E . Oct2005, Vol. 61 Issue 10, po3115-o3116. 1p. - Publication Year :
- 2005
-
Abstract
- The title compound, C42H41NOP2Si, used as a nixantphos-type ligand in homogeneous catalysis, crystallizes with one mol­ecule in the asymmetric unit. The mol­ecule has nearly mirror symmetry with N, O and Si on the pseudo-mirror plane, but it is not located on a crystallographic mirror plane. The most important feature of the mol­ecule is the intra­molecular P—P distance of 4.1453 (12) Å. The bond angles involving the P atoms are in the range 100.32 (14)–103.04 (15)°. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 61
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 18642729
- Full Text :
- https://doi.org/10.1107/S1600536805027121