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10-( tert-Butyl­dimethyl­silyl)-4,6-bis­(diphenyl­phosphino)phenoxazine.

Authors :
Haag, Rainer
Osiński, Piotr W.
Schürmann, Markus
Preut, Hans
Eilbracht, Peter
Source :
Acta Crystallographica: Section E. Oct2005, Vol. 61 Issue 10, po3115-o3116. 1p.
Publication Year :
2005

Abstract

The title compound, C42H41NOP2Si, used as a nixantphos-type ligand in homogeneous catalysis, crystallizes with one mol­ecule in the asymmetric unit. The mol­ecule has nearly mirror symmetry with N, O and Si on the pseudo-mirror plane, but it is not located on a crystallographic mirror plane. The most important feature of the mol­ecule is the intra­molecular P—P distance of 4.1453 (12) Å. The bond angles involving the P atoms are in the range 100.32 (14)–103.04 (15)°. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
10
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18642729
Full Text :
https://doi.org/10.1107/S1600536805027121