Quantitative elemental analysis and petrographic investigation of ancient potteries from archaeological sites of Tamil Nadu, using total reflection X-ray fluorescence spectroscopy.

In order to investigate the elemental composition, a total of 19 potteries and two representative clay samples from Senjikothamangalam (Villupuram district) and 12 potteries and one representative clay sample from the Palayanur (Chengalpattu) archaeological sites in Tamil Nadu were analyzed using total reflection X-ray fluorescence spectroscopy. The presence of elements such as Fe, Ca, K, Ti, Al, Sr, Mn, P, V, Cr, Zn, Rb, Ni, Cu, Pb, Ga, Y, Bi, Br, and As were identified in the pottery and clay samples. Statistical analysis, such as Pearson correlation, cluster and principal component analysis were used to categorize the samples based on their elemental composition. The outcome of the Pearson correlation and cluster analysis corroborated that the Senjikothamangalam pottery samples (P-1 to P-19) were made using the same type of clay, except P-10. Similarly, all Palayanur pottery samples (P-20 to P-31) were manufactured from the same clay. The petrographic analysis of the potteries revealed further information about its provenance and making methods. [ABSTRACT FROM AUTHOR]